Pre heat oven to 375° and position 2 racks in the upper and lower thirds of the oven.
Combine both kinds of chocolate and butter in a microwave safe bowl, and heat on high for 30 seconds. Remove, stir and return for another 30 seconds, stir again. If the chocolate is still quite solid, microwave for another 15-20 seconds, then remove and stir until the butter and the chocolate have been completely blended. Set aside to cool.
Add sugar, eggs and vanilla in another bowl, and whisk together by hand, until eggs and the sugar have been combined.
Add flour, cocoa powder, salt and baking powder in another bowl and blend with a wire whisk
Add egg mixture, stir with a fork or a whisk, then add the melted chocolate. Do not over mix.
Line 2 baking sheets with parchment paper and drop teaspoons full on the parchment, leaving room in between each to allow for spreading.
Bake in a pre heated oven for 6-8 minutes, switching the position of the baking sheets halfway through.
Allow to cool for at least 10 minutes before moving the whoopie pies.